Total Synthesis of (+)-Arteanniun M Using the Tandem Oxy-Cope/Ene Reaction
2001; American Chemical Society; Volume: 3; Issue: 12 Linguagem: Inglês
10.1021/ol015970l
ISSN1523-7060
AutoresLouis Barriault, Daniel H. Deon,
Tópico(s)Synthetic Organic Chemistry Methods
ResumoThe first total synthesis of (+)-arteannuin M was accomplished using the tandem oxy-Cope/transannular ene reaction as the key step to construct the bicyclic core of the natural product. The tandem reaction proceeded with high diastereo- and enantiomeric excess.
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