Photoredox Catalysis for Polymerization Reactions
2012; Swiss Chemical Society; Volume: 66; Issue: 6 Linguagem: Inglês
10.2533/chimia.2012.439
ISSN2673-2424
AutoresJacques Lalevée, Mohamad‐Ali Tehfe, Fabrice Morlet‐Savary, Bernadette Graff, Frédéric Dumur, Didier Gigmès, Nicolas Blanchard, Jean‐Pierre Fouassier,
Tópico(s)Chemistry and Chemical Engineering
ResumoPhotoredox catalysis is now well-known in organic synthesis for the formation of free radicals under very soft irradiations conditions (e.g. sunlight, household fluorescence or LED bulbs, Xe lamp). This method has been introduced here to the polymer chemistry area to initiate ring opening polymerizations (ROP) or free radical polymerizations (FRP). The present paper will give an up-to date situation of the photocatalyst achievements in FRP and ROP.
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