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Artigo Revisado por pares
BIBTEX RIS

Cyclic voltammetry of cryptands and cryptates containing the ferrocene unit

1995; Elsevier BV; Volume: 498; Issue: 2 Linguagem: Inglês

10.1016/0022-328x(95)05530-3

ISSN

1872-8561

Autores

C. Dennis Hall, Sunny Y.F. Chu,

Tópico(s)

Electrochemical Analysis and Applications

Resumo

Cyclic voltammetry studies of cryptands containing the ferrocene unit are reported, together with the shifts (ΔE12) in redox potential caused by complex formation with a variety of monovalent, divalent and trivalent cations. Correlation between δE12 values and the ratios charge (c)/cationic radius (r) for amide cryptands or c/r2 for amine cryptands are rationalised in terms of the type of complex formed.

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