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High-temperature chemical heat pump based on reversible catalytic reactions of cyclohexane-dehydrogenation/benzene-hydrogenation: Comparison of the potentialities of different flow diagrams

1993; Wiley; Volume: 17; Issue: 4 Linguagem: Inglês

10.1002/er.4440170406

1099-114X

Yu. I. Aristov, Valentin N. Parmon, G. Cacciola, N. Giordano,

Catalysis and Oxidation Reactions

International Journal of Energy ResearchVolume 17, Issue 4 p. 293-303 Article High-temperature chemical heat pump based on reversible catalytic reactions of cyclohexane-dehydrogenation/benzene-hydrogenation: Comparison of the potentialities of different flow diagrams Yuri I. Aristov, Yuri I. Aristov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences, Prospekt Akademika Laurentieva 5, 630090 Novosibirsk, RussiaSearch for more papers by this authorValentin N. Parmon, Valentin N. Parmon Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences, Prospekt Akademika Laurentieva 5, 630090 Novosibirsk, RussiaSearch for more papers by this authorGaetano Cacciola, Gaetano Cacciola Istituto CNR di Ricerche sui Metodi e Processi Chimici per la Trasformazione e l'Accumulo dell'Energia, Via Salita S. Lucia 39, 98126 S. Lucia-Messina, ItalySearch for more papers by this authorNicola Giordano, Nicola Giordano Istituto CNR di Ricerche sui Metodi e Processi Chimici per la Trasformazione e l'Accumulo dell'Energia, Via Salita S. Lucia 39, 98126 S. Lucia-Messina, ItalySearch for more papers by this author Yuri I. Aristov, Yuri I. Aristov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences, Prospekt Akademika Laurentieva 5, 630090 Novosibirsk, RussiaSearch for more papers by this authorValentin N. Parmon, Valentin N. Parmon Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences, Prospekt Akademika Laurentieva 5, 630090 Novosibirsk, RussiaSearch for more papers by this authorGaetano Cacciola, Gaetano Cacciola Istituto CNR di Ricerche sui Metodi e Processi Chimici per la Trasformazione e l'Accumulo dell'Energia, Via Salita S. Lucia 39, 98126 S. Lucia-Messina, ItalySearch for more papers by this authorNicola Giordano, Nicola Giordano Istituto CNR di Ricerche sui Metodi e Processi Chimici per la Trasformazione e l'Accumulo dell'Energia, Via Salita S. Lucia 39, 98126 S. Lucia-Messina, ItalySearch for more papers by this author First published: June 1993 https://doi.org/10.1002/er.4440170406Citations: 15AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Abstract The authors compare various flow diagrams for high temperature chemical heat pumps (HTCHP) based on the reversible cyclohexane-dehydrogenation/benzene-hydrogenation reactions. A new technological flow diagram for HTCHP is suggested. The peculiarity of this diagram is a multipurpose use of hydrogen-permeable membranes. A comparative thermodynamic analysis of the flow diagrams under consideration is undertaken in order to examine the influence of various factors on the heat efficiency and coefficient of performance of the heat pump. It is shown that the use of the hydrogen-permeable membranes in principle allows one to improve the performance of the HTCHPs and to extend the field of their application in comparison with the HTCHPs based on the flow diagrams suggested earlier. Referencess Andrews, H. I. (1955). 'The development of the solid-adsorption refrigerating machine for use on trains', Mod. Refr., 58, 381. Aristov, Yu. I., Cacciola, G., Parmon V. N. and Giordano, N. (1990). ' The influence of hydrogen-permeable membrane upon the efficiency of the high-temperature chemical heat pump based on the reversible catalytic reactions of cyclohexane dehydrogenation-benzene hydrogenation', Proceedings of 8th World Hydro Energy Conference, Honolulu, Pergamon Press, Vol. 3, pp. 1577– 1586. Buffington, R. M. (1933). 'Adsorption refrigeration with solid adsorbents', Refr. Engng., 26, 137. Cacciola, G., Restuccia, G. and Giordano, N. (1981). 'The catalytic reversible (de)hydrogenation of cyclohexane as a means for energy storage and chemical heat pump', Proceedings of International Conference on Energy storage, BHRA, Brighton, UK, 73– 89. Cacciola, G., Anikeev, V., Recupero, V., Kirillov, V. and Parmon, V. (1987). 'Chemical heat pump using heat of reversible catalytic reactions', Int. J. Energy Res., 11, 519– 529. Cacciola, G. and Recupero, V. (1980). 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Plank, R. and Vahl, L. (1931). 'Die thermishen Eigenschaften von Ammoniakaten und ahnlichen Verbindungen und ihre Verwendung in Absorptions-Kaltemaschinen', Forschung (Berlin) 2, (11). Suciu, D. F., Wicoff, P. M., Sanders R. D. and Toth, W. J. (1984). ' Survey and assessment of heat of reaction type chemical heat pumps', informal report EGG-PBS-6579, Idaho National Engineering Laboratory. Vahl, L. (1932). 'Methilamine as a refrigerant', Refr. Engng. 23, 351. Citing Literature Volume17, Issue4June 1993Pages 293-303 ReferencesRelatedInformation