Revision of the Structure of the Major Aggregation Pheromone of the Broad-horned Flour Beetle ( Gnatocerus cornutus ) to (1 S ,4 R ,5 R )-α-Acoradiene by Its Synthesis

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Revision of the Structure of the Major Aggregation Pheromone of the Broad-horned Flour Beetle ( Gnatocerus cornutus ) to (1 S ,4 R ,5 R )-α-Acoradiene by Its Synthesis

2004; Oxford University Press; Volume: 68; Issue: 3 Linguagem: Inglês

10.1271/bbb.68.663

ISSN

1347-6947

Autores

Takuya Tashiro, Satoshi Kurosawa, Kenji Mori,

Tópico(s)

Insect and Pesticide Research

Resumo

(1S,4R,5R)-(+)-alpha-acoradiene [1,8-dimethyl-4-(1-methylethenyl)spiro[4.5]dec-7-ene] (1) is shown by its synthesis to be the major component of the male-produced aggregation pheromone of the broad-horned flour beetle (Gnatocerus cornutus).

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Revision of the Structure of the Major Aggregation Pheromone of the Broad-horned Flour Beetle ( Gnatocerus cornutus ) to (1 S ,4 R ,5 R )-α-Acoradiene by Its Synthesis