Vinylphosphine: synthesis by flash vacuum pyrolysis, stability, and spectroscopic properties
1986; Royal Society of Chemistry; Issue: 18 Linguagem: Inglês
10.1039/c39860001428
ISSN2050-5639
AutoresMarie‐Claire Lasne, Jean‐Louis Ripoll, Andr� Thuillier,
Tópico(s)Porphyrin and Phthalocyanine Chemistry
ResumoVinylphosphine (1) has been synthesized from diethyl vinylphosphonate in three steps including a retro cycloaddition reaction using flash vacuum pyrolysis (overall yield ∼30%) and characterized by mass, i.r., and n.m.r. spectroscopy; it exhibits a remarkable stability at room temperature in neutral solution.
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