Voltar
Artigo Acesso aberto Revisado por pares
BIBTEX RIS

Monocyclopentadienyl alkyl alkylidene niobium(V) and tantalum(V) complexes. X-ray crystal structure of Ta(η5-Cp′)(CH2SiMe3)2(CHSiMe3)

1992; Elsevier BV; Volume: 11; Issue: 9 Linguagem: Inglês

10.1016/s0277-5387(00)84469-1

ISSN

1873-3719

Autores

I. Castro, F. Javier de la Mata, Manuel Gómez, Pilar Gómez‐Sal, Pascual Royo, José Manuel Selas,

Tópico(s)

Ferrocene Chemistry and Applications

Resumo

Reactions of monocyclopentadienyl complexes M(η5-Cp′)Cl4 with trimethylsilylmethyl lithium leads to the formation of alkylidene derivatives M(η5-Cp′)(CH2SiMe3)2(CHSiMe3), where M = Nb (1); Ta (2); Cp′= C5Me5 and M = Ta; Cp′ Me3Si(C5H4) (3), 1,3-(Me3Si)2(C5H3) (4). The new complexes were characterized by 1H and 13C NMR spectroscopy and the molecular structure of 2 was studied by X-ray diffraction methods.

Referência(s)