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BIBTEX RIS

Reactions of disiamyl(3-phenyl-2-butenyl)borane with aldehydes and ketones

1973; Elsevier BV; Volume: 51; Linguagem: Inglês

10.1016/s0022-328x(00)93503-4

ISSN

1872-8561

Autores

Indu Mehrotra, D. Devaprabhakara,

Tópico(s)

Advanced Synthetic Organic Chemistry

Resumo

A substituted allyl organoborane, disiamyl(3-phenyl-2-butenyl)borane has been prepared in situ by the monohydroboration of 3-phenyl-1,2-butadiene with disiamylborane. It reacts readily with butyraldehyde, benzaldehyde, acrolein and acetone to give unsaturated alcohols, possibly via a six-membered transition state involving allylic rearrangement.

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