Chirally templated boronic acid Mannich reaction in the synthesis of optically active α-amino acids

2000; Royal Society of Chemistry; Issue: 17 Linguagem: Inglês

10.1039/b003067h

ISSN

2050-8263

Autores

Gordon S. Currie, Michael G. B. Drew, Laurence M. Harwood, David Hughes, Richard Luke, Richard Vickers,

Tópico(s)

Chemical Synthesis and Analysis

Resumo

Adducts from diastereoselective Mannich-type reactions of aldehydes, 2-furylboronic acid and the chiral amine template (S)-5-phenylmorpholin-2-one, have been used in the synthesis of a series of enantiomerically pure D-α-amino acids.

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