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Artigo Revisado por pares
BIBTEX RIS

An Olefin Metathesis/Double Bond Isomerization Sequence Catalyzed by an In Situ Generated Ruthenium Hydride Species

2003; Wiley; Volume: 2003; Issue: 5 Linguagem: Inglês

10.1002/ejoc.200390124

ISSN

1434-193X

Autores

Bernd Schmidt,

Tópico(s)

Asymmetric Hydrogenation and Catalysis

Resumo

Abstract The direct conversion of allyl ethers to cyclic enol ethers using an olefin metathesis/double bond migration sequence is described. Ruthenium carbene complexes were activated to catalyze the double bond migration step by addition of hydride sources, such as NaH or NaBH 4 . (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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