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Photocatalytic Activity of PbS Quantum Dot/TiO 2 Nanotube Composites

2009; American Chemical Society; Volume: 113; Issue: 24 Linguagem: Inglês

10.1021/jp903050h

1932-7455

Chalita Ratanatawanate, Yuan Tao, Kenneth J. Balkus,

Quantum Dots Synthesis And Properties

PbS quantum dots (PbS QDs) were attached to TiO2 nanotubes on both the inside and outside surfaces of the nanotubes by using thiolactic acid, a bifunctional linker. The PbS QDs with diameters of 4−5 nm were controlled by adjusting the concentration of thiolactic acid. The PbS QDs can be placed only inside the nanotubes by first blocking the outer surface of the TNTs with the double-chain cationic surfactant. The photocatalytic activity and stability of PbS/TiO2 nanotubes were evaluated for the photodegradation of organic dyes. The results indicate that the functionalized TiO2 nanotubes were superior catalysts for photodegradation of cationic dyes. Additionally, the quantum dots enhance the activity and expand the usable portion of the solar spectrum.