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A Photochemical Approach to the Gelsemine Skeleton

1999; American Chemical Society; Volume: 1; Issue: 13 Linguagem: Inglês

10.1021/ol991119j

1523-7060

Anthony G. Avent, Paul Byrne, Clive S. Penkett,

Chemical synthesis and alkaloids

A silicon-tethered intramolecular meta photocycloaddition reaction was utilized to prepare a photoadduct, which was subsequently fragmented using m-CPBA to give a model for the skeleton of the alkaloid gelsemine.