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Synthesis and Structure of a Ga84R204− Cluster-A Link between Metalloid Clusters and Fullerenes?

2001; Wiley; Volume: 40; Issue: 4 Linguagem: Inglês

10.1002/1521-3773(20010216)40

1521-3773

Andreas Schnepf, Hansgeorg Schnöckel,

Inorganic Chemistry and Materials

Angewandte Chemie International EditionVolume 40, Issue 4 p. 711-715 Communication Synthesis and Structure of a Ga84R204− Cluster—A Link between Metalloid Clusters and Fullerenes? Andreas Schnepf Dr., Andreas Schnepf Dr. Institut für Anorganische Chemie der Universität Karlsruhe (TH) Engesserstrasse, Geb. 30.45, 76128 Karlsruhe, Germany, Fax: (+49) 721-608-4854Search for more papers by this authorHansgeorg Schnöckel Prof. Dr., Hansgeorg Schnöckel Prof. Dr. hg@achpc9.chemie.uni-karlsruhe.de Institut für Anorganische Chemie der Universität Karlsruhe (TH) Engesserstrasse, Geb. 30.45, 76128 Karlsruhe, Germany, Fax: (+49) 721-608-4854Search for more papers by this author Andreas Schnepf Dr., Andreas Schnepf Dr. Institut für Anorganische Chemie der Universität Karlsruhe (TH) Engesserstrasse, Geb. 30.45, 76128 Karlsruhe, Germany, Fax: (+49) 721-608-4854Search for more papers by this authorHansgeorg Schnöckel Prof. Dr., Hansgeorg Schnöckel Prof. Dr. hg@achpc9.chemie.uni-karlsruhe.de Institut für Anorganische Chemie der Universität Karlsruhe (TH) Engesserstrasse, Geb. 30.45, 76128 Karlsruhe, Germany, Fax: (+49) 721-608-4854Search for more papers by this author First published: 15 February 2001 https://doi.org/10.1002/1521-3773(20010216)40:4 3.0.CO;2-KCitations: 76 This work, which had originally been submitted to Nature in September 1999 and has been presented in part in lectures since January 2000, was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Abstract New record size! The reaction of Li[N(SiMe3)2] with a metastable solution of GaBr leads to good yields of [Ga84{N(SiMe3)2}20]4− (see picture), the largest Group 13 metalloid cluster that has been structurally characterized to date. On the basis of its highly symmetrical structure elements with predominantly covalent bonds, it is classified between the metalloid Al77 cluster and the fullerenes with respect to its bonding character. Citing Literature Volume40, Issue4February 16, 2001Pages 711-715 RelatedInformation