Reactions of β-Diketiminate-Stabilized Calcium Amides with 9-Borabicyclo[3.3.1]nonane (9-BBN)
2007; American Chemical Society; Volume: 26; Issue: 16 Linguagem: Inglês
10.1021/om070083t
ISSN1520-6041
AutoresAnthony G. M. Barrett, Mark R. Crimmin, Michael S. Hill, Peter B. Hitchcock, Panayiotis A. Procopiou,
Tópico(s)Synthetic Organic Chemistry Methods
ResumoThe reaction of a β-diketiminate-stabilized calcium diphenylamide with the dialkylborane 9-BBN allows the synthesis of a β-diketiminate-stabilized calcium borohydride along with an amidoborane reaction coproduct via a likely σ-bond metathesis mechanism.
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