Thermodynamics of acetone—chloroform mixtures
1980; Elsevier BV; Volume: 4; Issue: 3-4 Linguagem: Inglês
10.1016/0378-3812(80)80018-5
ISSN1879-0224
AutoresAlexander Apelblat, Abraham Tamir, Moshe Wagner,
Tópico(s)Phase Equilibria and Thermodynamics
ResumoApelblat, A., Tamir, A. and Wagner, M., 1980. Thermodynamics of acetone—chloroform mixtures. Fluid Phase Equilibria, 4: 229–255. The excess thermodynamic functions GE, HE, SE, CpE and VE and the vapour—liquid equilibria at constant temperature, at constant pressure and azeotropic behaviour are satisfactorily described for the acetone + chloroform system using the ideal association model of the type A + B + AB + AB2. Existing data in the literature for the system were supplemented by determination of vapour pressures at 25.0° and 35.17°C, excess volumes of mixing at 35°C and excess heat capacities at 30°C.
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