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BIBTEX RIS

MgCl and Mg 2 Cl 2 : From Theoretical and Thermodynamic Considerations to Spectroscopy and Chemistry of Species with MgMg Bonds

2008; Wiley; Volume: 47; Issue: 45 Linguagem: Inglês

10.1002/anie.200802960

ISSN

1521-3773

Autores

Ralf Köppe, Patrick Henke, Hansgeorg Schnöckel,

Tópico(s)

Hydrogen Storage and Materials

Resumo

Happy together: When HCl is passed over heated MgB2, the magnesium subhalide MgCl is formed, which converts into the dimeric linear MgMg species Mg2Cl2 upon matrix isolation. The two compounds were characterized by vibrational spectroscopy and by computations; special attention was given to the MgMg bond. The results are compared to recent findings concerning ligand-stabilized MgMg species.

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