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Electrical and chemical characteristics of nano-meter gold encapsulated in mesoporous and microporous channels and cages of FSM-16 and Y zeolites

2002; Elsevier BV; Volume: 64; Issue: 2 Linguagem: Inglês

10.1016/s0022-3697(02)00300-1

1879-2553

Mohamed Mokhtar Mohamed, I. Mekkawy,

Electrochemical Analysis and Applications

Abstract The dc and ac conductivities as well as the dielectric constant ( e ) were measured for different zeolites encapsulated gold (AuCl3) samples at different temperatures (300–500 K) and various frequencies (5 kHz–1 MHz). The conductivity was found to change in the order Au/FSM-27>Au/NaY>Au/FSM-47. Sorbed water contained inside zeolites assists greatly the proton mobility (zeolite protons) and the ion mobility (Na+ and Au+) and hence enhance the electric conduction in the temperature range 300–373 K. Raising the temperature over 373 K induces dehydration effect that assists the metallic gold formation and thus a dramatic loss in conductivity was revealed. The conduction mechanism was expected to be partially ionic and partially electronic. The IR study showed that the exposure of Au zeolites to CO gas produced a characteristic band of Au+–CO at 2180 cm−1 that tends to decrease with temperatures and even vanishes at 376 K in favor of Au0–CO at 2128 cm−1. Similarly, a phase transition at 338 K, that occurs in the range 300–376 K, was confirmed by DTA to further emphasize the temperature regions of either Au+ cations (338 K) or Au0 (376 K) formation.