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High yield direct fluorofunctionalisation of ketones using AccufluorTM-NFTh fluorinating reagent

1996; Elsevier BV; Volume: 37; Issue: 20 Linguagem: Inglês

10.1016/0040-4039(96)00630-2

1873-3581

Stojan Stavber, Marko Zupan,

Synthesis and Catalytic Reactions

Direct regioselective conversion of a variety of cyclic and acyclic ketones to α-fluoroketones was achieved in high to excellent yield using 1-fluoro-4-hydroxy-1,4-diazoniabicyclo[2,2,2]octane bis(tetrafluoroborate) [AccufluorTM - NFTh] in acetonitrile solution.