Cu(II) catalyzed hydrolysis of an unactivated ester based on reversible conjugate addition11Presented at the 197th American Chemical Society National Meeting, Dallas, TX, April 1989.
1989; Elsevier BV; Volume: 30; Issue: 50 Linguagem: Inglês
10.1016/s0040-4039(01)93395-7
ISSN1873-3581
AutoresBrook F. Duerr, Anthony W. Czarnik,
Tópico(s)Synthetic Organic Chemistry Methods
ResumoCu(II) catalysis provides a 16,000-fold acceleration in the hydrolysis of methyl acrylate when a removable vicinal diamine ligand is used to increase the stability of the required copper chelate.
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