New formal synthesis of (±)-estrone
1990; Issue: 5 Linguagem: Inglês
10.1039/p19900001331
ISSN2050-8255
AutoresN. M. SUNDER, Prakash A. Patil, N. S. Narasimhan,
Tópico(s)Microbial Natural Products and Biosynthesis
Resumo(±)-Estrone is synthesised via Torgov's compound by an AB→ABC→ABCD route. The C-ring is constructed by a new Diels–Alder methodology and the D-ring by a novel cyclopentane annulation reaction from a cyclopropanol precursor.
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