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Hypervalent iodine in organic synthesis. A new route to α-functionalized carboxylate esters.

1981; Elsevier BV; Volume: 22; Issue: 29 Linguagem: Inglês

10.1016/s0040-4039(01)90541-6

1873-3581

Robert M. Moriarty, Henry Hu,

Synthesis and Reactions of Organic Compounds

Aryl and alkylcarboxylate esters are converted into the corresponding α-hydroxy acids or α-alkoxyesters upon treatment with C6H5I(OAc)2 and base in the appropriate solvent.