Artigo Revisado por pares

A Ratiometric Fluorescent Chemodosimeter with Selective Recognition for Sulfite in Aqueous Solution

2009; American Chemical Society; Volume: 74; Issue: 20 Linguagem: Inglês

10.1021/jo9014744

ISSN

1520-6904

Autores

Yimin Sun, Cheng Zhong, Rui Gong, Honglei Mu, Enqin Fu,

Tópico(s)

Sulfur Compounds in Biology

Resumo

A fluorescent chemodosimeter containing a guanidiniocarbonylpyrrole and a 9-(aminomethyl)anthracene moiety has been synthesized. The sensor exhibits ratiometric fluorescence changes for SO(3)(2-) over other anions in 90% water/DMSO. The interesting ratiometric fluorescent changes for SO(3)(2-) are attributed to the fluorescence resonance energy transfer (FRET) and the SO(3)(2-) complex induced photochemical reaction.

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