A Ratiometric Fluorescent Chemodosimeter with Selective Recognition for Sulfite in Aqueous Solution
2009; American Chemical Society; Volume: 74; Issue: 20 Linguagem: Inglês
10.1021/jo9014744
ISSN1520-6904
AutoresYimin Sun, Cheng Zhong, Rui Gong, Honglei Mu, Enqin Fu,
Tópico(s)Sulfur Compounds in Biology
ResumoA fluorescent chemodosimeter containing a guanidiniocarbonylpyrrole and a 9-(aminomethyl)anthracene moiety has been synthesized. The sensor exhibits ratiometric fluorescence changes for SO(3)(2-) over other anions in 90% water/DMSO. The interesting ratiometric fluorescent changes for SO(3)(2-) are attributed to the fluorescence resonance energy transfer (FRET) and the SO(3)(2-) complex induced photochemical reaction.
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