Versatile direct dehydrative approach for diaryliodonium(iii) salts in fluoroalcohol media
2007; Royal Society of Chemistry; Issue: 40 Linguagem: Inglês
10.1039/b708802g
ISSN1364-548X
AutoresToshifumi Dohi, Motoki Ito, Koji Morimoto, Yutaka Minamitsuji, Naoko Takenaga, Yasuyuki Kita,
Tópico(s)Vanadium and Halogenation Chemistry
ResumoWe have found that the use of fluoroalcohol media greatly enhanced the efficiency and scope of the direct dehydrative condensation of arenes and hypervalent iodine(III) compounds; the present clean method has a broad range of applicability as well as unique selectivity in the aromatic substrates, and is highly efficient even in polymer functionalization.
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