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In situ NMR study of the rhodium(I)-catalyzed hydrogenation of the allene 1-methoxy-propa-1,2-diene using parahydrogen

1994; Elsevier BV; Volume: 35; Issue: 42 Linguagem: Inglês

10.1016/0040-4039(94)80110-x

1873-3581

Andreas Harthun, Joachim Bargon, Rüdiger Selke,

Hydrogen Storage and Materials

1. The homogeneous hydrogenation of 1-methoxy-propa-1,2-diene was investigated via in situ 1H-NMR spectroscopy using different rhodium(I) catalysts and parahydrogen (p-H2). 2. The detected polarization signals allow the determination of the hydrogenation products due to their characteristic patterns.