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Further evidence of SET mechanism during the LAH reduction of optically active 1-bromo 1-methyl 2,2-diphenyl cyclopropane.

1986; Elsevier BV; Volume: 27; Issue: 32 Linguagem: Inglês

10.1016/s0040-4039(00)83863-0

1873-3581

Jacques Hatem, J.M. Meslem, B. Waegell,

Photochemistry and Electron Transfer Studies

Abstract The stereochemical outcome of the reduction of 1(−) (R) with TBTH, SMEAH or LAH shows that with the latter a radical intermediate is involved.