Portal de Periódicos da CAPES

Photoelectron Spectra of F2O and Cl2O

1971; American Institute of Physics; Volume: 55; Issue: 6 Linguagem: Inglês

10.1063/1.1676498

1520-9032

A. B. Cornford, D.C. Frost, F. G. Herring, C. A. McDowell,

Atmospheric Ozone and Climate

The valence ionization potentials of F2O and Cl2O have been determined by photoelectron spectrometry, and the results are compared with the predictions of ab initio and approximate LCAO SCF calculations. The first PES band shows vibrational structure which is assigned to ν1 for F2O, and to both ν1 and ν2 for (Cl2O). These frequencies all show slight increases over the corresponding values for the ground states of the neutral molecules.