A simple and efficient CCSD(T)-F12 approximation
2007; American Institute of Physics; Volume: 127; Issue: 22 Linguagem: Inglês
10.1063/1.2817618
ISSN1520-9032
AutoresThomas B. Adler, Gerald Knizia, Hans‐Joachim Werner,
Tópico(s)Molecular spectroscopy and chirality
ResumoA new explicitly correlated CCSD(T)-F12 approximation is presented and tested for 23 molecules and 15 chemical reactions. The F12 correction strongly improves the basis set convergence of correlation and reaction energies. Errors of the Hartree-Fock contributions are effectively removed by including MP2 single excitations into the auxiliary basis set. Using aug-cc-pVTZ basis sets the CCSD(T)-F12 calculations are more accurate and two orders of magnitude faster than standard CCSD(T)/aug-cc-pV5Z calculations.
Referência(s)