Octahedral complexes of uranium(IV). II. Magnetic and spectral effects of tetragonal distortion
1969; Elsevier BV; Volume: 3; Linguagem: Inglês
10.1016/s0020-1693(00)92487-3
ISSN1873-3255
AutoresBattery Lane, Luigi M. Venanzi,
Tópico(s)Solid-state spectroscopy and crystallography
ResumoThe electronic spectra and magnetic susceptibilities of the complexes [UCl4L2] and [UBr4L2] (L = Et3PO, Ph3AsO, Et3AsO) have been measured. Relative values of the nephelauxetic and ligand field effects for these and similar complexes have been derived and used to explain the magnetic behaviour. Infrared data is reported in support of the proposed structures.
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