Peptide Synthesis in Aqueous Solution. V. Properties and Reactivities of ( p -Hydroxyphenyl)benzylmethylsulfonium Salts for Direct Benzyl Esterification of N -Acylpeptides
1996; Oxford University Press; Volume: 69; Issue: 4 Linguagem: Inglês
10.1246/bcsj.69.1099
ISSN1348-0634
AutoresTakashi Nakata, Masaru Nakatani, Masatoshi Takahashi, Jiro Okai, Yoshiaki Kawaoka, Katsushige Kouge, Hideo Okai,
Tópico(s)Analytical Chemistry and Chromatography
ResumoAbstract Some (p-hydroxyphenyl)benzylmethylsulfonium salts were prepared. These compounds generated a benzyl cation and converted not only N-acylamino acids but also N-acylpeptides into their corresponding benzyl esters without causing the racemization.
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