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Composite Solids Constructed From One‐Dimensional Coordination Polymer Matrices and Molybdenum Oxide Subunits: Polyoxomolybdate Clusters within [{Cu(4,4′‐bpy)} 4 Mo 8 O 26 ] and [{Ni(H 2 O) 2 (4,4′‐bpy) 2 } 2 Mo 8 O 26 ] and One‐Dimensional Oxide Chains in [{Cu(4,4′‐bpy)} 4 Mo 15 O 47 ]·8H 2 O

1997; Wiley; Volume: 36; Issue: 8 Linguagem: Inglês

10.1002/anie.199708731

1521-3773

Douglas Hagrman, Chloe Zubeita, David J. Rose, Chloé Zubieta, Robert C. Haushalter,

Metal-Organic Frameworks: Synthesis and Applications

Angewandte Chemie International Edition in EnglishVolume 36, Issue 8 p. 873-876 Communication Composite Solids Constructed From One-Dimensional Coordination Polymer Matrices and Molybdenum Oxide Subunits: Polyoxomolybdate Clusters within [{Cu(4,4′-bpy)}4Mo8O26] and [{Ni(H2O)2(4,4′-bpy)2}2Mo8O26] and One-Dimensional Oxide Chains in [{Cu(4,4′-bpy)}4Mo15O47]·8H2O† Douglas Hagrman, Douglas Hagrman Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected]Search for more papers by this authorChloe Zubeita, Chloe Zubeita Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected]Search for more papers by this authorDr. David J. Rose, Dr. David J. Rose Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected]Search for more papers by this authorProf. Jon Zubieta, Corresponding Author Prof. Jon Zubieta Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected] Jon Zubieta, Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected] Robert C. Haushalter, NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA)Search for more papers by this authorDr. Robert C. Haushalter, Corresponding Author Dr. Robert C. Haushalter NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA) Jon Zubieta, Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected] Robert C. Haushalter, NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA)Search for more papers by this author Douglas Hagrman, Douglas Hagrman Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected]Search for more papers by this authorChloe Zubeita, Chloe Zubeita Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected]Search for more papers by this authorDr. David J. Rose, Dr. David J. Rose Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected]Search for more papers by this authorProf. Jon Zubieta, Corresponding Author Prof. Jon Zubieta Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected] Jon Zubieta, Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected] Robert C. Haushalter, NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA)Search for more papers by this authorDr. Robert C. Haushalter, Corresponding Author Dr. Robert C. Haushalter NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA) Jon Zubieta, Department of Chemistry, Syracuse University, Syracuse, NY 13244 (USA), Fax: Int. code +(315)443-4070, e-mail: [email protected] Robert C. Haushalter, NEC Research Institute, 4 Independence Way, Princeton, NJ 08540 (USA)Search for more papers by this author First published: May 2, 1997 https://doi.org/10.1002/anie.199708731Citations: 400 † The work at Syracuse was supported by the U. S. National Science Foundation (grant no. CHE 9318824). AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Soft chemical methods were used for preparing the new class of composite materials presented here. One example is [{Cu(4,4′-bpy)}4Mo8O26] (4,4′-bpy = 4,4′-bipyridine), whose unique structure (shown on the right) consists of [Mo8O26]4− clusters embedded in a web of {Cu(4,4′-bpy)} one-dimensional chains. Citing Literature Volume36, Issue8May 2, 1997Pages 873-876 RelatedInformation