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Molekül‐ und KristallStruktur des Dioxano‐bis(2,4‐dichlorphenoxyacetato)‐kupfer(II) Cu 2 (2,4‐D) 4 · 5 Dioxan

1979; Wiley; Volume: 321; Issue: 4 Linguagem: Inglês

10.1002/prac.19793210406

0021-8383

G. Reck, Wolfgang Jähnig,

Organometallic Complex Synthesis and Catalysis

Molecular and Crystal Structure of Dioxano‐bis(2,4‐dichlorophenoxyacetato)‐copper (II) Cu 2 (2,4‐D) 4 · 5 Dioxan The cupric salt of 2,4‐D crystallizes from dioxane solution in the space group P 1 with 2 formula units C 16 H 10 O 6 Cl 4 Cu and 5 dioxane molecules in the unit cell. The lattice constants are a = 12.557 Å, b = 14.391 Å, c = 9.537 Å, α = 112.56°, β = 99.62° and γ = 92.77°. By X‐ray structure analysis the coordination around the Cu atoms was especially investigated.