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Vapor‐liquid equilibrium: Part V. Data reduction by maximum likelihood

1978; Wiley; Volume: 24; Issue: 6 Linguagem: Inglês

10.1002/aic.690240617

1547-5905

Hendrick C. Van Ness, Finn Skou Pedersen, Peter Rasmussen,

Advanced Thermodynamics and Statistical Mechanics

Abstract A systematic study is presented of the objective functions applicable to the reduction of vapor‐liquid equilibrium data by regression procedures based on the principle of maximum likelihood. Numerical results are based on a set of artificial x ‐ y ‐ P data constructed so as to conform to the assumptions that underlie proper application of this principle.