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The complex scaling method: Application to autoionization, predissociation, and multiphoton resonances

1986; Wiley; Volume: 30; Issue: S20 Linguagem: Inglês

10.1002/qua.560300715

1097-461X

Shih‐I Chu,

Advanced Chemical Physics Studies

Several recent extensions of the method of complex scaling to the studies of autoionization, predissociation, and multiphoton dynamics will be presented. Specific subjects to be discussed include: 1 Complex-coordinate coupled-Landau-channel method for autoionizing resonances and photoinization of atomic hydrogen in intense magnetic fields, 2 Non-Hermitian complex quasi-energy method for multiphoton dissociation of small molecules with specific application to two-photon dissociation of vibrationally excited H2+ and HD+, and 3 Vibrational predissociation of highly vibrationally excited He—I (v) van der Waals molecules.