The search for new biochemical photoprobes. II. The nucleophilic photosubstitution of 2-fluoro-4-nitroanisole.
1989; Elsevier BV; Volume: 45; Issue: 24 Linguagem: Inglês
10.1016/s0040-4020(01)85796-3
ISSN1464-5416
AutoresRoser Pleixats, Marta Figueredo, Jordi Marquet, Marcial Moreno‐Mañas, Albert Cantos,
Tópico(s)Organic Chemistry Cycloaddition Reactions
ResumoThe photosubstitutions of 2-fluoro-4-nitroanisole with several amines are studied. The preparative results, the thermal stability of the photochemical substrate, and the limiting quantum yield values obtained from photoreactions with several nucleophiles suggest the possible usefulness of 2-fluoro-4-nitrophenyl ethers as biochemical photoprobes.
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