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Formation of molecular hydrogen complexes of iron by the reversible protonation of iron dihydrides with alcohols

1988; Royal Society of Chemistry; Issue: 8 Linguagem: Inglês

10.1039/c39880000546

2050-5639

Murray V. Baker, Leslie D. Field, David James Young,

Chemical Reactions and Isotopes

Reversible protonation of cis-FeH2(PP)2[PP = R2PCH2CH2PR2] complexes by ethanol produces the η2-co-ordinated molecular hydrogen complexes trans-FeH(H2)(PP)2+ which readily undergo substitution with loss of H2.