Enantiomeric excess determination of some chiral sulfoxides by NMR: use of (S)-Ibuprofen® and (S)-Naproxen® as shift reagents
1997; Elsevier BV; Volume: 38; Issue: 45 Linguagem: Inglês
10.1016/s0040-4039(97)10153-8
ISSN1873-3581
AutoresLaëtitia Fauconnot, Caroline Nugier‐Chauvin, Nicolas Noiret, Henri Patin,
Tópico(s)Analytical Chemistry and Chromatography
ResumoAbstract The well known drugs (S)-Ibuprofen and (S)-Naproxen were used as NMR shift reagents for the stereochemical analysis of alkylsulfoxides. It was shown that (S)-Naproxen could be worthwhile substituted to (S)-MPA or (S)-2-NMA for the stereochemical analysis of some chiral alkyl sulfoxides.
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