Synthesis and Characterization of New Red-Emitting Polyfluorene Derivatives Containing Electron-Deficient 2-Pyran-4-ylidene−Malononitrile Moieties
2003; American Chemical Society; Volume: 37; Issue: 2 Linguagem: Inglês
10.1021/ma0355397
ISSN1520-5835
AutoresQiang Peng, Zhiyun Lu, Yan Huang, Minggui Xie, Shaohu Han, Junbiao Peng, Yong Cao,
Tópico(s)Conducting polymers and applications
ResumoA novel series of red-light-emitting copolymers derived from fluorene and 2-pyran-4-ylidene−malononitrile (PM) have been synthesized through a palladium-catalyzed Suzuki coupling reaction. The polymers were characterized by FT-IR, NMR, and elemental analysis. All these polymers are completely soluble in common organic solvents, such as THF, CH2Cl2, CHCl3, and toluene, and they have good thermal stability with onset decomposition temperature (Td) of 406−407 °C and glass-transition temperature (Tg) of 73−186 °C. Cyclic voltanmetry studies reveal that these copolymers have low-lying LUMO energy levels ranging from −3.53 to −3.57 eV and HOMO energy levels ranging from −5.77 to −5.79 eV, which indicated that they may be promising candidates for electron-transporting or hole-blocking materials in light-emitting diodes. These polymers in thin films can emit strong red photoluminescence (PL) around 641−662 nm with the corresponding additional peaks in the range 704−712 nm upon photoexcitation. Double-layer LEDs fabricated with the configuration of ITO/PEDOT/polymer/Ba/Al can emit red light with external quantum efficiencies of 0.21−0.38%. Preliminary electroluminescent (EL) results show that these polymers are novel promising candidates for red emissive materials in polymer light-emitting diodes.
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