A two-dimensional framework of novel vanadium clusters bridged by [Ni(en)2]2+: K{V12IVV6VO42Cl[Ni(en)2]3}·8H2O
2003; Royal Society of Chemistry; Issue: 4 Linguagem: Inglês
10.1039/b211530c
ISSN1477-9234
AutoresCheng‐Ling Pan, Ji‐Qing Xu, Guanghua Li, Xiao‐Bing Cui, Ling Ye, Guang-Di Yang,
Tópico(s)Vanadium and Halogenation Chemistry
ResumoThe hydrothermal reaction of V2O5, H2C2O4·2H2O, en, KOH and NiCl2·6H2O gives a new two-dimensional open-framework solid; the extended structure consists of a two-dimensional network formed by the interconnection of each [V18O42Cl] cage to four other neighboring units via six [Ni(en)2]2+ bridging groups.
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