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Simple Preparation of 1-Bromo-1-Trimethylsilyl-1(Z), 4-pentadiene and its Use as 4-Pentenoyl Anion Equivalent

1982; Taylor & Francis; Volume: 12; Issue: 13 Linguagem: Inglês

10.1080/00397918208061944

1532-2432

Ryohei Yamaguchi, Hiroto Kawasaki, Mituyosi Kawanisi,

History and advancements in chemistry

Abstract The titled compound is easily obtained by palladium (II)-catalyzed bromoallylation of ethynyltrimethylsilane and can serve as 4-pentenoyl anion equivalent which is a valuable synthetic grouping.