Ratio of the glass transition temperature to the melting point in polymers

1970; Wiley; Volume: 2; Issue: 1 Linguagem: Inglês

10.1002/pi.4980020112

ISSN

1934-256X

Autores

W. A. Lee, G. J. Knight,

Tópico(s)

Advanced Mathematical Theories and Applications

Resumo

Abstract A study of the ratio of the glass temperature to the melting point of 132 polymers is described. Contrary to some other workers' observations on smaller numbers of polymers there is no sharp division between the ratios observed for symmetrical and unsymmetrical polymers. The arithmetic mean of the ratio is 0·63 and 0·69 respectively, but the combined standard deviation is 0·11. There is no correlation between the ratios and the crystalline forms of polymers.

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