Specific Interaction between Chloroform and the Pockets of Triangular Annulene Derivatives Providing Symmetry Carry‐Over Crystallization
2009; Wiley; Volume: 15; Issue: 48 Linguagem: Inglês
10.1002/chem.200901848
ISSN1521-3765
AutoresIchiro Hisaki, H. Senga, Yuu Sakamoto, Seiji Tsuzuki, Norimitsu Tohnai, Mikiji Miyata,
Tópico(s)Fullerene Chemistry and Applications
ResumoChemistry – A European JournalVolume 15, Issue 48 p. 13336-13340 Communication Specific Interaction between Chloroform and the Pockets of Triangular Annulene Derivatives Providing Symmetry Carry-Over Crystallization Ichiro Hisaki Dr., Ichiro Hisaki Dr. hisaki@mls.eng.osaka-u.ac.jp Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7406Search for more papers by this authorHirofumi Senga, Hirofumi Senga Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7406Search for more papers by this authorYuu Sakamoto, Yuu Sakamoto Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7406Search for more papers by this authorSeiji Tsuzuki Dr., Seiji Tsuzuki Dr. s.tsuzuki@aist.go.jp Research Institute of Computational Sciences, National Institute of Advanced Industrial Science and Technology, Tsukuba Ibaraki 305-8568 (Japan), Fax: (+81) 29-851-5426Search for more papers by this authorNorimitsu Tohnai Dr., Norimitsu Tohnai Dr. Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7406Search for more papers by this authorMikiji Miyata Prof. Dr., Mikiji Miyata Prof. Dr. miyata@mls.eng.osaka-u.ac.jp Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7406Search for more papers by this author Ichiro Hisaki Dr., Ichiro Hisaki Dr. hisaki@mls.eng.osaka-u.ac.jp Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7406Search for more papers by this authorHirofumi Senga, Hirofumi Senga Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7406Search for more papers by this authorYuu Sakamoto, Yuu Sakamoto Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7406Search for more papers by this authorSeiji Tsuzuki Dr., Seiji Tsuzuki Dr. s.tsuzuki@aist.go.jp Research Institute of Computational Sciences, National Institute of Advanced Industrial Science and Technology, Tsukuba Ibaraki 305-8568 (Japan), Fax: (+81) 29-851-5426Search for more papers by this authorNorimitsu Tohnai Dr., Norimitsu Tohnai Dr. Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7406Search for more papers by this authorMikiji Miyata Prof. Dr., Mikiji Miyata Prof. Dr. miyata@mls.eng.osaka-u.ac.jp Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7406Search for more papers by this author First published: 08 December 2009 https://doi.org/10.1002/chem.200901848Citations: 21Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract What's it got in its pockets? Symmetry carry-over crystallization of hexadehydrotribenzo[12]annulene derivatives was provided by specific complexation between the annulene and the chloroform molecule through mainly dispersion forces (see picture). In the complex, a hydrogen atom of the chloroform fits into the annulene's "pocket" surrounded by π electrons. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description chem_200901848_sm_miscellaneous_information.pdf4.3 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume15, Issue48December 14, 2009Pages 13336-13340 RelatedInformation
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