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BIBTEX RIS

NH 2 -MIL-53(Al): A High-Contrast Reversible Solid-State Nonlinear Optical Switch

2012; American Chemical Society; Volume: 134; Issue: 20 Linguagem: Inglês

10.1021/ja300655f

ISSN

1943-2984

Autores

Pablo Serra‐Crespo, Monique A. Van Der Veen, Elena Gobechiya, Kristof Houthoofd, Yaroslav Filinchuk, Christine E. A. Kirschhock, Johan A. Martens, Bert F. Sels, Dirk De Vos, Freek Kapteijn, Jorge Gascón,

Tópico(s)

Crystal Structures and Properties

Resumo

The metal–organic framework NH2-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.

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