Preparation and characterization of N,N-diacetatodithiocarbamato metal complexes with large negative charges
2012; Elsevier BV; Volume: 394; Linguagem: Inglês
10.1016/j.ica.2012.08.028
ISSN1873-3255
AutoresKeo Vanthoeun, Toh Bunho, Ryoji Mitsuhashi, Takayoshi Suzuki, Masakazu Kita,
Tópico(s)Metal complexes synthesis and properties
ResumoNew metal complexes with N,N-diacetatodithiocarbamate (Ac2dtc3−), Na6[Co(Ac2dtc)3], Ba3[Co(Ac2dtc)3], Na4[Ni(Ac2dtc)2], Ba2[Ni(Ac2dtc)2], Na4[Cu(Ac2dtc)2] and Ba2[Cu(Ac2dtc)2], have been synthesized, and their molecular structures and spectroscopic properties have been characterized. The X-ray analysis of Ba3[Co(Ac2dtc)3]·16H2O confirmed a well-organized and rigid network among carboxyl groups of the complex anions, barium cations, and water molecules.
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