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Catalytic Asymmetric α‐Hydroxyamination of Carbonyls with N ‐Hydroxycarbamates Becomes Greener

2014; Wiley; Volume: 6; Issue: 7 Linguagem: Inglês

10.1002/cctc.201402121

1867-3899

Chenguang Yu, Aiguo Song, Fang Zhang, Wei Wang,

Asymmetric Synthesis and Catalysis

ChemCatChemVolume 6, Issue 7 p. 1863-1865 Highlight Catalytic Asymmetric α-Hydroxyamination of Carbonyls with N-Hydroxycarbamates Becomes Greener Chenguang Yu, Chenguang Yu Department of Chemistry & Chemical Biology, University of New Mexico, MSC03 2060, Albuquerque, NM 87131 (USA), Fax: (+1) 505-277-2609Search for more papers by this authorAiguo Song, Aiguo Song Department of Chemistry & Chemical Biology, University of New Mexico, MSC03 2060, Albuquerque, NM 87131 (USA), Fax: (+1) 505-277-2609Search for more papers by this authorProf. Dr. Fang Zhang, Corresponding Author Prof. Dr. Fang Zhang zhangfang@shnu.edu.cn Department of Chemistry & Chemical Biology, University of New Mexico, MSC03 2060, Albuquerque, NM 87131 (USA), Fax: (+1) 505-277-2609 The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai, 200234 (China)Department of Chemistry & Chemical Biology, University of New Mexico, MSC03 2060, Albuquerque, NM 87131 (USA), Fax: (+1) 505-277-2609===Search for more papers by this authorProf. Dr. Wei Wang, Corresponding Author Prof. Dr. Wei Wang wwang@unm.edu Department of Chemistry & Chemical Biology, University of New Mexico, MSC03 2060, Albuquerque, NM 87131 (USA), Fax: (+1) 505-277-2609Department of Chemistry & Chemical Biology, University of New Mexico, MSC03 2060, Albuquerque, NM 87131 (USA), Fax: (+1) 505-277-2609===Search for more papers by this author Chenguang Yu, Chenguang Yu Department of Chemistry & Chemical Biology, University of New Mexico, MSC03 2060, Albuquerque, NM 87131 (USA), Fax: (+1) 505-277-2609Search for more papers by this authorAiguo Song, Aiguo Song Department of Chemistry & Chemical Biology, University of New Mexico, MSC03 2060, Albuquerque, NM 87131 (USA), Fax: (+1) 505-277-2609Search for more papers by this authorProf. Dr. Fang Zhang, Corresponding Author Prof. Dr. Fang Zhang zhangfang@shnu.edu.cn Department of Chemistry & Chemical Biology, University of New Mexico, MSC03 2060, Albuquerque, NM 87131 (USA), Fax: (+1) 505-277-2609 The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai, 200234 (China)Department of Chemistry & Chemical Biology, University of New Mexico, MSC03 2060, Albuquerque, NM 87131 (USA), Fax: (+1) 505-277-2609===Search for more papers by this authorProf. Dr. Wei Wang, Corresponding Author Prof. Dr. Wei Wang wwang@unm.edu Department of Chemistry & Chemical Biology, University of New Mexico, MSC03 2060, Albuquerque, NM 87131 (USA), Fax: (+1) 505-277-2609Department of Chemistry & Chemical Biology, University of New Mexico, MSC03 2060, Albuquerque, NM 87131 (USA), Fax: (+1) 505-277-2609===Search for more papers by this author First published: 02 June 2014 https://doi.org/10.1002/cctc.201402121Citations: 13Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract The power of two: A highly enantio- and regioselective aminocatalytic and Lewis acid catalyzed α-hydroxyamination of β-keto esters and 1,3-diketones with N-hydroxycarbamates is realized in "one-pot" under aerobic conditions. The powerful dual catalysis strategy opens opportunities for developing new efficient organic transformations. Cbz=Benzyloxycarbonyl, Boc=tert-butoxycarbonyl. Citing Literature Volume6, Issue7July 2014Pages 1863-1865 RelatedInformation