Synthesis of Trialkylsilylated α-Hydroperoxy Aldehydes and Ketones via Ozonolysis of Protected Allylic Hydroperoxides
1989; Thieme Medical Publishers (Germany); Volume: 1989; Issue: 02 Linguagem: Inglês
10.1055/s-1989-27167
ISSN1437-210X
AutoresWaldemar Adam, Luiz Henrique Catalani, Chantu R. Saha‐Möller, Bernd Will,
Tópico(s)Fluorine in Organic Chemistry
Resumoα-Silylperoxy aldehydes and ketones 3 have been prepared by ozonolysis of silyl-protected allylic hydroperoxides, followed by subsequent reduction of the latter with dimethyl sulfide. Deprotection of silylperoxy aldehydes 3a-c with fluoride ion led to decomposition with chemiluminescence.
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