Radical oxidative decarboxylation of α-hydroxylactones. Influence of oxygen-carbon β-bond effect
1995; Elsevier BV; Volume: 36; Issue: 12 Linguagem: Inglês
10.1016/0040-4039(95)00196-j
ISSN1873-3581
AutoresCosme G. Francisco, Renato S. Freire, Mariá S. Rodríguez, Ernesto Suárez,
Tópico(s)Chemical Synthesis and Reactions
Resumoα-Hydroxylactones undergo decarboxylation when submitted to the system (diacetoxyiodo)benzene (DIB)/iodine under mild conditions. β-Oxygen substituents were observed to deactivate the decarboxylation reaction.
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