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Comparison between Experimental and Theoretical Estimations of the Thermal Expansion, Concentration Expansion Coefficients, and Viscosity for Binary Mixtures under Pressures up to 20 MPa

2009; American Chemical Society; Volume: 54; Issue: 6 Linguagem: Inglês

10.1021/je8008073

1520-5134

Henri Bataller, Christelle Miqueu, Frédéric Plantier, Jean‐Luc Daridon, T. J. Jaber, Alireza Abbasi, M. Ziad Saghir, M. Mounir Bou‐Ali,

Chemical Thermodynamics and Molecular Structure

In this work, we have measured the densities of binary mixtures of n-dodecane, 1-phenyl-2-methylpropane, and 1,2,3,4-tetrahydronaphthalene for pressures varying from (0.1 to 20) MPa at an average temperature of 25 °C. By a derivative method, we have determined the thermal expansion and concentration expansion coefficients for binary mixtures of equal mass fraction. In addition, viscosities have been measured and compared with theoretical estimates. To accurately predict the thermal expansion and concentration expansion coefficients, the densities of the binary mixtures were calculated using PC-SAFT, Peng-Robinson, and volume translated Peng-Robinson equations of state. The comparison with measured densities showed that PC-SAFT has a better agreement with experimental data than the other equations of state. From calculated densities we evaluated the thermal expansion and concentration expansion variation coefficients. We have found that PC-SAFT gives a suitable prediction for the two derivative properties unlike the two other equations of state. The combination of the model of Lohrenz-Bray-Clark for the viscosity of liquid mixtures and the densities calculated with the three equations of state gave a poor prediction of the viscosities of the binary mixtures.