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Al-substituted α-nickel hydroxide prepared by homogeneous precipitation method with urea

2003; Elsevier BV; Volume: 29; Issue: 8 Linguagem: Inglês

10.1016/j.ijhydene.2003.10.006

1879-3487

Yue Zhao, J. M. Wang, Huafeng Chen, Tao Pan, J. Q. Zhang, C. N. Cao,

Advancements in Battery Materials

Al-substituted α-nickel hydroxide was prepared by homogeneous precipitation from nickel nitrate solution in the presence of urea. The experimental results of XRD and FTIR show that the Ni(OH)2 samples prepared by this method are typical α-phase. The 0% Al-containing α-Ni(OH)2 is labile in alkaline media and easily converted to β-Ni(OH)2. The stability of the samples increases with increase in Al content. The SEM results show that the 0% Al-containing sample contain spherical particles with some degree of agglomeration, while the 16.8% Al-containing sample displays an irregular shape. The galvanostatic charge–discharge experiments show that the discharge potential of Al-substituted α-Ni(OH)2 increases with increase in Al content. However, the maximum discharge capacities decrease slightly with increasing Al content at the 0.1C rate. The Al-substituted α-Ni(OH)2 samples have better activation performance than the 0% Al-containing sample at the 0.1C rate. At the 1.0C rate, the 19.5% Al-containing sample has the highest discharge capacity and relatively better cycle stability.