Pyrochlore solid solutions (LaxY1−x)2Mo2O7, x = 0.0 to 0.5. Spin-glass-like behavior
1987; Elsevier BV; Volume: 67; Issue: 2 Linguagem: Inglês
10.1016/0022-4596(87)90360-4
ISSN1095-726X
Autores Tópico(s)Radioactive element chemistry and processing
ResumoThe (LaxY1−x)2Mo2O7 system was investigated in the range x = 0.0 to x = 0.5. Single-phase materials exist up to x = 0.4; the x = 0.5 composition has a small impurity contamination. The lattice constants are linear with x and range from 10.224 Å (x = 0.0) to 10.461 Å (x = 0.5). These lattice constants span the same range as the R2Mo2O7 series from R = Y to R = Nd. In this series, there is a discontinuous change from ferromagnetic long-range order to short-range spin-glass-like order between R = Gd and R = Tb. Yet, the solid solutions all show spin-glass-like properties with maxima in the susceptibility in the 20–25 K range and sample-history-dependent effects at lower temperatures. Deviations from the Curie-Weiss Law occur well above the susceptibility maxima. The Weiss constants change from −61 to +41 K for x = 0.0 and x = 0.5, respectively, indicating a competition between antiferromagnetic and ferromagnetic exchange interactions. This competition, coupled with the inherent frustration of the Mo4+ lattice in space group Fd3m is a possible origin of the spin-glass properties.
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