A convenient new synthesis of α-fluorocarbonyl compounds
1979; Elsevier BV; Volume: 20; Issue: 36 Linguagem: Inglês
10.1016/s0040-4039(01)95408-5
ISSN1873-3581
Autores Tópico(s)Synthetic Organic Chemistry Methods
ResumoThe reaction between tertiary α-bromo ketones or aldehydes and silver tetrafluoroborate in ether affords α-fluorocarbonyl compounds. Neighboring group participation by the carbonyl oxygen is proposed to account for the products and by-products.
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